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The structure of the title compound, C(23)H(21)OPSe(2), consists of fused puckered five- and six-membered rings, PSeC(2)O and C(5)O, respectively, with a C(2)O bridgehead. The C(5)O ring adopts a chair conformation, whilst the C(2)PSeO ring has an envelope conformation.

1,5,6-Triphenyl-8-oxa-7-selena-6-phosphabicyclo[3.2.1]octane-6-selone