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The title compound, C25H20N4&#183;4H2O, crystallizes with the organic molecule lying on a twofold rotation axis through the methylene bridge C atom; there are also two water molecules in the asymmetric unit. The crystal structure is stabilized by C&#8212;H...O, O&#8212;H...O and O&#8212;H...N hydrogen bonds, linking the water molecules to each other and to the pyridine N atom

N-[(E)-4-Pyridylmethylene]-4-[(E)-4-(4-pyridylmethyleneamino)benzyl]aniline tetrahydrate