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In the title compound, C(18)H(24)NO(2) (+)·Cl(-), the absolute configuration of the new stereogenic centre (the C atom with a CH(2)OH substituent) was unambiguously determined to have an R configuration. The dihedral angle between the two aromatic rings is 30.82 (2)°. Inter-molecular N-H⋯Cl and O-H⋯Cl hydrogen bonds and intra-molecular N-H⋯O hydrogen bonds stabilize the crystal structure.

N-[(S)-1-(3,5-Dimethyl-2-hydroxyphenyl)ethyl]-N-[(R)-2-hydroxy-1-phenylethyl]ammonium chloride