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In the crystal structure of the title compound, [Cu2(N3)2(C10H8N2)]n, each CuI atom is coordinated by two symmetry-related azide anions and 4,4&#8242;-bipyridine (bipy) ligands in a strongly distorted tetrahedral geometry. The Cu atom and the azide anion occupy general positions while the bipy molecule is located on a centre of inversion. Each two symmetry-related copper(I) cations and two symmetry-related azide anions form dimers, which are additionally connected by the anions into layers. These layers are linked by the 4,4&#8242;-bipyridine ligands into a three-dimensional coordination network

Poly[di-μ3-azido-μ2-4,4′-bipyridine-dicopper(I)]

Poly[di-μ₃-azido-μ₂-4,4′-bipyridine-dicopper(I)]