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The racemic title compound, C27H26N2O4, crystallizes with its central carbon bridge on a twofold axis. It forms parallel chains of molecules utilizing aryl offset face&#8211;face interactions with an interplanar distance of about 3.5&#8197;&#197;. These chains associate further by means of pairs of O&#8212;CH2&#8212;H...&#960; (with H&#8211;ring distances ranging from 2.69 to 2.95&#8197;&#197;) and O&#8212;CH2&#8212;H...N motifs. The methoxy groups in this structure are coplanar with the aromatic rings to which they are attached. This is recognized as being common behaviour amongst aromatic methoxy compounds

2,3,10,11-Tetramethoxy-6,7,14,15-tetrahydro-6,14-methanocycloocta[1,2-b;5,6-b′]diquinoline