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In the title compound, C18H24O4S, the chiral bicyclo[2.2.1]heptane group is not symmetrical due to the influence of the substituents. The angle between the three-atom bridge plane and the four-atom planes of the boat-shaped six-membered ring are 55.07&#8197;(19) and 56.24&#8197;(19)&#176;. The bridgehead angle is 92.75&#8197;(17)&#176;

(1R,4R,7S)-1,7-Dimethyl-7-(phenylsulfonylmethyl)spiro[bicyclo[2.2.1]heptane-2,2′-1,3-dioxolane]