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The title compound, C10H14N4O6, crystallizes with two independent molecules in the asymmetric unit. An extensive network of N&#8212;H...O and C&#8212;H...O intermolecular hydrogen bonds stabilizes the crystal packing. One ethyl group is disordered over two positions; the site occupancy factors are 0.68 and 0.32

3α,6α-Bis(ethoxycarbonyl)glycoluril (diethyl 2,5-dioxoperhydroimidazo[4,5-d]imidazole-3a,6a-dicarboxylate)