Open Access1‐Chloromethyl‐4‐aza‐1‐azoniabicyclo[2.2.2]octane tetrafluoroborate deuterochloroform solvate
Author(s) -
Batsanov Andrei S.,
Trmcic Jelena,
Sandford Graham
Publication year - 2005
Publication title -
acta crystallographica section e
Language(s) - English
Resource type - Journals
ISSN - 1600-5368
DOI - 10.1107/s1600536805004411
Subject(s) - octane , tetrafluoroborate , chemistry , solvent , ion , medicinal chemistry , symmetry (geometry) , stereochemistry , crystallography , organic chemistry , catalysis , ionic liquid , geometry , mathematics
The title structure, C 7 H 14 ClN 2 + ·BF 4 − ·CDCl 3 , comprises 1‐chloromethyl‐4‐aza‐1‐azoniabicyclo[2.2.2]octane cations, BF 4 − anions and CDCl 3 solvent molecules, each having C s crystallographic symmetry. The cation has a staggered conformation and the anion and solvent molecule are connected via a C—D⋯F interaction.