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alcohol by a coordination polymer involving insertion/de-insertion of the alcohol into a Ag-O(carboxylate) bond will be described.[4] The presentation will further develop the results of recently published work with discussion of ongoing studies of the two systems. [1] S. J. Delgarno et al., Chem. Soc. Rev. 2007, 36, 236. [2] G. Minguez Espallargas et al., J. Am. Chem. Soc. 2006, 128, 9584. [3] G. Minguez Espallargas et al., J. Am. Chem. Soc. 2007, 129, 15606. [4] S. Libri et al., Angew Chem. Int. Ed. 2008, 47, 1693.

What are the molecular properties that influence the formation of methanol solvates?