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two distinct shapes. X-ray diffraction has shown these two crystals to be different forms (orthorhombic and cubic) of a cationic cluster of composition [Cu21(sacc)6(phen)12]. The penta-anionic saccharate adopts a different binding mode in each of the copper clusters. The spaces between the copper clusters are also of interest. The cubic form has a cell length of 73.7 Å and each unit cell contains a void with an approximate volume of 30,000Å. 1. Abrahams, B.F.; Moylan, M.D.; Orchard, S.D.; Robson, R., Angew Chem Int Ed, 2003, 42, 1848.

A novel chiral metal-organic framework that catalyses asymmetric reaction in the chiral open space