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24 European Crystallographic Meeting, ECM24, Marrakech, 2007 Page s156 Acta Cryst. (2007). A63, s156 It was shown that optical properties of both 1 and 2 correlate with the local ligand environments observed in the crystal structures. In both cases, the rigidity of the stilbene linker increases upon coordination to the inorganic units through inhibition of torsion about the central ethylene bond, resulting in luminescent crystals with increased emission lifetimes compared to solutions of trans-stilbene. The emission spectrum of 2 is found to depend on the nature of the incorporated solvent molecules, suggesting use of this or related materials in sensor applications.

Hydrogen bond in tri(2-hydroxyanilinium) hexachlorostin (IV) chloride trihydrate