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24 European Crystallographic Meeting, ECM24, Marrakech, 2007 Page s222 Acta Cryst. (2007). A63, s222 MS25 P06 Unit-cell volume dependent study of disordered fluoride pyrochlores Andrzej Grzechnik, Jose Maria Posse, Wolfgang Morgenroth, Reinhard Kaindl, Karen Friese Departamento de Física de la Materia Condensada, Universidad del País Vasco, Bilbao, Spain; Institut für Anorganische Chemie, Georg August Universität, Göttingen, Germany; Department of Chemistry, Aarhus University, Denmark; ChristianDoppler-Laboratory for Advanced Hard Coatings, University of Innsbruck, Austria. E-mail: andrzej@wm.lc.ehu.es