Overlooked problems in manifold twins: twin misfit in zero‐obliquity TLQS twinning and twin index calculation
Author(s) -
Ferraris Giovanni,
Nespolo Massimo
Publication year - 2007
Publication title -
acta crystallographica section a
Language(s) - English
Resource type - Journals
eISSN - 1600-5724
pISSN - 0108-7673
DOI - 10.1107/s0108767307012135
Subject(s) - lattice (music) , crystal twinning , mathematics , geometry , physics , crystallography , chemistry , microstructure , acoustics
It is shown that the twin index n calculated, according to Friedel, as a function of the indices ( hkl ) and [ uvw ] of the lattice plane and lattice direction defining the cell of the twin lattice applies only to twofold twins, i.e . twins where the twin element is of order 2. For manifold twins, where the twin operation is a three‐, four‐ or sixfold (direct or inverse) rotation, it is shown that the generalized formula becomes n = N Ξ/ξ, where N is the number of lattice planes of the ( hkl ) family passing within the cell of the twin lattice, Ξ the two‐dimensional coincidence index for a plane of the ( hkl ) family and ξ the number of planes out of N of that family that are partially restored by the twin operation. The existence of twin lattice quasi‐symmetry (TLQS) twins with zero‐obliquity in manifold twins leads to the introduction of a new parameter as a general measure of the pseudo‐symmetry of TLQS rotation twins: the twin misfit δ , defined as the distance between the first nodes along the two shortest directions in the plane of L T (quasi‐)perpendicular to the twin axes that are quasi‐restored by the twin operation. Taking the example of staurolite twins, several inconsistencies in the treatment of manifold twins are pointed out.
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