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Structural and thermal expansion studies of Li2ZrO3 were carried out by recording X-ray powder diffraction patterns at ®ve temperatures, 82, 198, 300, 423 and 573 K. The Rietveld re®nement method was used for the analysis. There were large anisotropic changes in the lattice parameters as a function of temperature, slight changes in the fractional coordinates of the different atoms, and anisotropic changes in the interatomic distances between the different cations. The correlation of these anisotropies with the structure is considered.

Structural and Anisotropic Thermal Expansion Correlation of Li2ZrO3at Different Temperatures

Structural and Anisotropic Thermal Expansion Correlation of Li₂ZrO₃at Different Temperatures