Open AccessIntramolecular N—H⋯O, intermolecular O—H⋯O, C—H⋯O and C sp 3 —H⋯π arene interactions in (2 S )‐2‐{[(2 R )‐2‐hydroxy‐2‐phenylethanoyl]amino}‐4‐methylpentanoic acid
Author(s) -
Dalton J. P.,
Gallagher J. F.,
Penny P. T. M.,
O'Donohue M.
Publication year - 1999
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
eISSN - 1600-5759
pISSN - 0108-2701
DOI - 10.1107/s0108270198010063
Subject(s) - intramolecular force , intermolecular force , hydrogen bond , chemistry , stereochemistry , solid state , crystallography , molecule , organic chemistry
The title compound, C₁₄H₁₉NO₄, forms a hydrogenbonded\udnetwork in the solid state, consisting of one intramolecular N--H...O [N...O 2.569 (3)Å] and two intermolecular O--H...0=C [O...O 2.704(2) and 2.801 (2)Å] hydrogen bonds, with weaker C--H...O [C...O 3.344(3)Å] and Csp³--H...πarene [shortest C...C 3.873 (4)Å] interactions completing the three-dimensional network
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