[η 6 ‐1‐Chloro‐2‐(pyrrolidin‐1‐yl)benzene](η 5 ‐cyclopentadienyl)iron(II) hexafluoridophosphate and (η 5 ‐cyclopentadienyl){2‐[η 6 ‐2‐(pyrrolidin‐1‐yl)phenyl]phenol}iron(II) hexafluoridophosphate

In the complex salt [η 6 ‐1‐chloro‐2‐(pyrrolidin‐1‐yl)benzene](η 5 ‐cyclopentadienyl)iron(II) hexafluoridophosphate, [Fe(C 5 H 5 )(C 10 H 12 ClN)]PF 6 , (I), the complexed cyclopentadienyl and benzene rings are almost parallel, with a dihedral angle between their planes of 2.3 (3)°. In a related complex salt, (η 5 ‐cyclopentadienyl){2‐[η 6 ‐2‐(pyrrolidin‐1‐yl)phenyl]phenol}iron(II) hexafluoridophosphate, [Fe(C 5 H 5 )(C 16 H 17 NO)]PF 6 , (II), the analogous angle is 5.4 (1)°. In both complexes, the aromatic C atom bound to the pyrrolidine N atom is located out of the plane defined by the remaining five ring C atoms. The dihedral angles between the plane of these five ring atoms and a plane defined by the N‐bound aromatic C atom and two neighboring C atoms are 9.7 (8) and 5.6 (2)° for (I) and (II), respectively.