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1,6‐Interactions between dimethylamino and aldehyde groups in two biphenyl derivatives
Author(s) -
O'Leary Jane,
Wallis John D.,
Wood Michael L.
Publication year - 2001
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
eISSN - 1600-5759
pISSN - 0108-2701
DOI - 10.1107/s0108270101006369
Subject(s) - biphenyl , aldehyde , chemistry , medicinal chemistry , stereochemistry , organic chemistry , catalysis
The title compounds, 2‐(dimethylamino)biphenyl‐2′‐carboxaldehyde, C 15 H 15 NO, and 2‐(dimethylamino)biphenyl‐2′,6′‐dicarboxaldehyde, C 16 H 15 NO 2 , show similar 1,6‐interactions [N⋯C=O 2.929 (3) to 3.029 (3) Å] between the dimethylamino and aldehyde groups located in the ortho positions of the two rings, which lie at 58.1 (1)–62.4 (1)° to each other.

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