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Cuprates and iron-based superconductors are two classes of unconventionalhigh Tc superconductors based on 3d transition elements. Recently, twoprinciples, correspondence principle and magnetic selective pairing rule, havebeen emerged to unify their high Tc superconducting mechanisms. Theseprinciples strongly regulate electronic structures that can host high Tcsuperconductivity. Guided by these principles, here we propose high Tcsuperconducting candidates that are formed by cation-anion trigonal bipyramidalcomplexes with a d^7 filling configuration on the cation ions. Theirsuperconducting states are expected to be dominated by the d+id pairingsymmetry.

Predicting Unconventional High Temperature Superconductors in Trigonal Bipyramidal Coordinations