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The lanthanide pyrochlore oxides Ln$_2$B$_2$O$_7$ are one of the mostintensely studied classes of materials within condensed matter physics, firmlycentered as one of the pillars of frustrated magnetism. The extensive chemicaldiversity of the pyrochlores, coupled with their innate geometric frustration,enables realization of a wide array of exotic and complex magnetic groundstates. Thus, the discovery of new pyrochlore compositions has been apersistent theme that continues to drive the field in exciting directions. Therecent focus on the mixed B-site pyrochlores offers a unique route towardstuning both local coordination chemistry and sterics, while maintaining anominally pristine magnetic sublattice. Here, we present a broad overview ofthe pyrochlore stability field, integrating recent synthetic efforts in mixedB-site systems with the historically established Ln$_2$B$_2$O$_7$ families. Inparallel, we present the discovery and synthesis of the entire Ln$_2$InSbO$_7$family (Ln: La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) located nearthe boundary of the pyrochlore stability field using a rapid, hybridmechanicochemical/microwave-assisted synthesis technique. Magneticcharacterization on the entire class of compounds draws striking parallels tothe stannate analogs, suggesting that these compounds may host a breadth ofexotic magnetic ground states.

Traversing the pyrochlore stability diagram; microwave-assisted synthesis and discovery of mixed B-site Ln$_2$InSbO$_7$ family