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This paper was supported by Engineering and Physical Sciences Research Council (EPSRC) Grants No. EP/K503162/1, No. EP/M506631/1, No. EP/M025330/1, No. EP/L017008/1, No. EP/K022237/1, No. EP/K015540/1, and No. EP/I036079/1. RUS facilities in Cambridge were established through grants to M.A.C. from the EPSRC and the Natural Environment Research Council (Grants No. NE/B505738/1 and No. NE/F17081/1). A portion of this research used resources at the Spallation Neutron Source, a U.S. Department of Energy Office of Science User Facility operated by the Oak Ridge National Laboratory (ORNL). I.D.W.S. acknowledges funding from a Royal Society Wolfson research merit award.

Role of lattice distortion and A site cation in the phase transitions of methylammonium lead halide perovskites