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Here we show that the low temperature phase of magnetite is associated withan effective, although fractional, ordering of the charge. Evidence and aquantitative evaluation of the atomic charges are achieved by using resonantx-ray diffraction (RXD) experiments whose results are further analyzed with thehelp of ab initio calculations of the scattering factors involved. Byconfirming the results obtained from X-ray crystallography we have shown thatRXD is able to probe quantitatively the electronic structure in very complexoxides, whose importance covers a wide domain of applications.Comment: 4 pages 4 figures, accepted for publication in PR

Resonant X-Ray Diffraction Studies on the Charge Ordering in Magnetite