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The 2p-3d core hole interaction in the L2,3 absorption spectra of the 3dtransition metals is treated within time-dependent density functional theory(TDDFT). A simple three-level model explains the origin of the strongdeviations from the one-particle branching ratio and yields matrix elements ofthe unknown exchange-correlation (XC) kernel directly from experiment

physical review letters

Measuring the Kernel of Time-Dependent Density Functional Theory with X-Ray Absorption Spectroscopy of<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mn>3</mml:mn><mml:mi>d</mml:mi></mml:math>Transition Metals

Measuring the Kernel of Time-Dependent Density Functional Theory with X-Ray Absorption Spectroscopy of3dTransition Metals