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We have performed multicanonical chain-growth simulations of a polymerinteracting with an adsorbing surface. The polymer, which is not explicitlyanchored at the surface, experiences a hierarchy of phase transitions betweenconformations binding and non-binding with the substrate. We discuss the phasediagram in the temperature-solubility plane and highlight the transition``path'' through the free-energy landscape.

Conformational Transitions of Nongrafted Polymers near an Absorbing Substrate