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Using an electrochemically gated transistor, we achieved controlled andreversible doping of poly(p-phenylene vinylene) in a large concentration range.Our data open a wide energy-window view on the density of states (DOS) andshow, for the first time, that the core of the DOS function is Gaussian, whilethe low-energy tail has a more complex structure. The hole mobility increasesby more than four orders of magnitude when the electrochemical potential isscanned through the DOS.

physical review letters

Wide Energy-Window View on the Density of States and Hole Mobility in Poly(<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mi>p</mml:mi></mml:math>-Phenylene Vinylene)

Wide Energy-Window View on the Density of States and Hole Mobility in Poly(p-Phenylene Vinylene)