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A relationship between the time scales of quantum coherence loss andshort-time solvent response for a solute/bath system is derived for a Gaussianwave packet approximation for the bath. Decoherence and solvent response timesare shown to be directly proportional to each other, with the proportionalitycoefficient given by the ratio of the thermal energy fluctuations to thefluctuations in the system-bath coupling. The relationship allows theprediction of decoherence times for condensed phase chemical systems from welldeveloped experimental methods.Comment: 10 pages, no figures, late

Relationship between Quantum Decoherence Times and Solvation Dynamics in Condensed Phase Chemical Systems