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Enhanced population transfer from the lowest to the highest level in the three-state ladder 5s→5p→5d of the rubidium atom by frequency-swept ultrashort laser pulses is observed if the frequency sweep first makes the pulse resonant with the 5s→5p transition, and later with the 5p→5d transition. With this «intuitive» scheme it is possible to achieve complete population inversion via the intermediate level by two successive adiabatic passages. Complete inversion is also obtained by a «counterintuitive» direction of the frequency sweep, in which case population of the intermediate level during the pulse is strongly reduced

Efficient population transfer in a three-level ladder system by frequency-swept ultrashort laser pulses