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The first observation of the elusive Fe4+ charge state coming from the nuclear decay of 57Co3+ has been found in the Mössbauer emission spectra of 57Co:La2Li0.5Co0.5O4. A Ti-doped sample was prepared in order to show that the Fe4+ fraction can be conveniently monitored. Both results were predicted on the basis of the electronic energy-band scheme of these oxides

physical review letters

Evidence of the Anomalous Charge State<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:mmultiscripts><mml:mrow><mml:mi mathvariant="normal">Fe</mml:mi></mml:mrow><mml:mrow /><mml:mrow><mml:mn>4</mml:mn><mml:mo>+</mml:mo></mml:mrow><mml:mrow /><mml:mrow /><mml:mprescripts /><mml:mrow /><mml:mrow><mml:mn>57</mml:mn></mml:mrow><mml:mrow /><mml:mrow /></mml:mmultiscripts></mml:mrow></mml:math>in the Nuclear Decay of<mml:math xmlns:mml="http://www.w3.org/1998/…

Evidence of the Anomalous Charge StateFe4+57in the Nuclear Decay of