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Photoelectron spectra from atomic barium were recorded following excitation with synchrotron radiation at selected autoionization resonance energies. The greatly enhanced intensities of peaks arising from certain levels in Ba/sup +/ elucidate the structures of the autoionizing levels and implicate Auger decay as the dominant mode for their interaction with the continuum. Resonance photoelectron spectroscopy shows promise of wide applicability.

Selective Resonant Enhancement of Electron-Correlation Satellites in Atomic Barium