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Multilayer sorption isotherms of 1-propanol on graphite have been measured bymeans of high-resolution ellipsometry within the liquid regime of the adsorbedfilm for temperatures ranging from 180 to 260 K. In the first three monolayersthe molecules are oriented parallel to the substrate and the growth is roughlyconsistent with the Frenkel-Halsey-Hill-model (FHH) that is obeyed invan-der-Waals systems on strong substrates. The condensation of the fourth andhigher layers is delayed with respect to the FHH-model. The fourth layer isactually a bilayer. Furthermore there is indication of a wetting transition.The results are interpreted in terms of hydrogen-bridge bonding within andbetween the layers.

Transition from van-der-Waals to H Bonds dominated Interaction in n-Propanol physisorbed on Graphite