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The optical transition linewidth and emission polarization of singlenitrogen-vacancy (NV) centers are measured from 5 K to room temperature.Inter-excited state population relaxation is shown to broaden the zero-phononline and both the relaxation and linewidth are found to follow a T^5 dependencefor T up to 100 K. This dependence indicates that the dynamic Jahn-Tellereffect is the dominant dephasing mechanism for the NV optical transitions atlow temperatures.

Observation of the dynamic Jahn-Teller effect in the excited states of nitrogen-vacancy centers in diamond