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A new hight Tc Fe-based compound system, AFe2As2 with A = K, Cs, K/Sr andCs/Sr has been found. Through electron-doping, Tc of the A = K and Cs compoundsrises to ~37 K, and finally enter a spin-density-wave state (SDW) throughfurther electron doping with Sr. The observation demonstrates the crucial roleof the (FeAs)-layers in the superconductivity in the Fe-based layered systemand the special feature of elemental A-layers in this complex chemical systemmay provide new avenues to superconductivity at a higher Tc.

Superconductivity up to 37 K in (A1-xSrx)Fe2As2 with A=K and Cs