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We develop the first comprehensive approach to model associating fluids withsmall bond angles using Wertheim's perturbation theory. We show theoreticallyand through monte carlo simulations that as bond angle is varied various modesof association become dominant. The new theory is shown to be in excellentagreement with monte carlo simulation for the prediction of the internalenergy, pressure and fractions in rings, chains, double bonded over the fullrange of bond angles.

Thermodynamic perturbation theory for associating fluids with small bond angles: Effects of steric hindrance, ring formation and double bonding