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Irreversible thermodynamics provides interface conditions that yield temperature and chemical potential jumps at phase boundaries. The interfacial jumps allow unexpected transport phenomena, such as the inverted temperature profile [ Pao Phys. Fluids 14 306 (1971)] and mass transfer from a cold to a warm liquid driven by a temperature difference across the vapor phase [ Mills and Phillips Chem. Phys. Lett. 372 615 (2002)]. Careful evaluation of the thermodynamic laws has shown [ Bedeaux et al. Physica A 169 263 (1990)] that the inverted temperature profile is observed for processes with a high heat of vaporization. In this paper, we show that cold to warm mass transfer through the vapor from a cold to a warm liquid is only possible when the heat of evaporation is sufficiently small. A necessary criterium for the size of the mass transfer coefficient is given

Temperature-difference-driven mass transfer through the vapor from a cold to a warm liquid