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Near-critical binary mixtures containing ionic solutes near a charged wallpreferentially adsorbing one component of the solvent are studied. Within theLandau-Ginzburg approach extended to include electrostatic interactions and thechemical preference of ions for one component of the solvent, we obtain asimple form for the leading-order correction to the Debye-Huckel theory resultfor the charge density profile. Our result shows that critical adsorptioninfluences significantly distribution of ions near the wall. This effect mayhave important implications for the screening of electrostatic interactionsbetween charged surfaces immersed in binary near-critical solvents.

Distribution of ions near a charged selective surface in critical binary solvents