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We present the first experimental observation of K$_{\beta}$ emission fromhighly charged Mg ions at solid density, driven by intense x-rays from a freeelectron laser. The presence of K$_{\beta}$ emission indicates the $n=3$ atomicshell is relocalized for high charge states, providing an upper constraint onthe depression of the ionization potential. We explore the process of staterelocalization in dense plasmas from first principles using finite-temperaturedensity functional theory alongside a wavefunction localization metric, andfind excellent agreement with experimental results.

Investigating Mechanisms of State Localization in Highly-Ionized Dense Plasmas