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We propose to measure the surface charge accumulating at the interfacebetween a plasma and a dielectric by infrared spectroscopy using the dielectricas a multi-internal reflection element. The surplus charge leads to anattenuation of the transmitted signal from which the magnitude of the chargecan be inferred. Calculating the optical response perturbatively in first orderfrom the Boltzmann equation for the electron-hole plasma inside the solid, wecan show that in the parameter range of interest a classical Drude termresults. Only the integrated surface charge enters, opening up thereby a veryefficient analysis of measured data.

Infrared spectroscopy of surface charges in plasma-facing dielectrics