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Using the Parsons Lee theory we examined the effect of shape anisotropy andthe wall to wall separation on the phase behavior of the hard parallelepipedrods with dimensions L, D, and D (L>D) in such narrow slitlike pores which onlyone homeotropic layer can form. The phase structures, including biaxiality,planar nematic layering transition as well as planar to homeotropic, werestudied for some separations in the range 2.5D<H<10.0D for H-D<L<H.

physical review. e

From n-layer planar ordering to the monolayer homeotropic structure of  confined hard rods: The effect of shape anisotropy and wall-to-wall  separation