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The {\gamma}-emission probability of the 66.73 keV line in the decay of 171Tmhas been experimentally determined using {\gamma}-spectrometry and inductivelycoupled mass spectrometry. Using a set of two reference sources, namely 60Co asprimary standard and 44Ti/44Sc in secular equilibrium as secondary standards,we were able to deduce the detection efficiency at 67.87 keV of the used{\gamma}-spectrometry setup with high precision. The emission probability ofthe 66.73 keV {\gamma}-transition in the decay of 171Tm has been determinedwith a set of three radioisotopically pure 171Tm samples to be 0.159(6) %.

On the emission probability of the 66.7 keV {\gamma}-transition in the decay of 171Tm