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Mass measurements on radionuclides along the potassium isotope chain havebeen performed with the ISOLTRAP Penning trap mass spectrometer. For 35KT1/2=178ms) to 46K (T1/2=105s) relative mass uncertainties of 2x10-8 and betterhave been achieved. The accurate mass determination of 35K (dm=0.54keV) hasbeen exploited to test the Isobaric Multiplet Mass Equation (IMME) for theA=35, T=3/2 isospinquartet. The experimental results indicate a deviation fromthe generally adopted quadratic form.

Evidence for a breakdown of the Isobaric Multiplet Mass Equation: A study of the A=35, T=3/2 isospin quartet