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The magnetic susceptibility, crystal and magnetic structures, and electronicstructure of double perovskite Sr2ScOsO6 are reported. Using both neutron andx-ray powder diffraction we find that the crystal structure is monoclinic P21/nfrom 3.5 to 300 K. Magnetization measurements indicate an antiferromagnetictransition at TN=92K, one of the highest transition temperatures of any doubleperovskite hosting only one magnetic ion. Type I antiferromagnetic order isdetermined by neutron powder diffraction, with an Os moment of only 1.6(1) muB,close to half the spin-only value for a crystal field split 5d electron statewith t2g^3 ground state. Density functional calculations show that thisreduction is largely the result of strong Os-O hybridization, with spin-orbitcoupling responsible for only a ~0.1 muB reduction in the moment.

Magnetic order and electronic structure of 5d3 double perovskite Sr2ScOsO6