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We demonstrate that contrary to the common belief the critical temperature Tcof clean F1/S/F2 spin valves can depend non-monotonically on the angle betweenthe magnetic moments of the ferromagnetic F1 and F2 layers. Depending on thesystem parameters the minimum of Tc may correspond to parallel, antiparallel ornon-collinear mutual orientation of magnetic moments. Such anomalous behaviorcan reveal itself only provided the ferromagnetic layers differ from each otherand it completely disappears in the dirty limit.

Standard, inverse and triplet spin-valve effects in F1/S/F2 systems