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We present an ab initio GW calculation to study dynamical effects on anorganic compound (TMTSF)2PF6. Calculated polarized reflectivities reproduceexperimental plasma edges at around 0.2 eV for E||b' and 1.0 eV for E||a. Thelow-energy plasmons come out from the low-energy narrow bands energeticallyisolated from other higher-energy bands, and affect the low-energy electronicstructure via the GW-type self-energy. Because of the quasi-one-dimensionalband structure, a large plasmon-induced electron scattering is found in thelow-energy occupied states along the X-M line.

Ab initio GW calculation for organic compounds (TMTSF)2PF6