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The one-dimensional reconstruction of Au/Ge(001) was investigated by means ofautocorrelation functions from surface x-ray diffraction (SXRD) and scanningtunneling microscopy (STM). Interatomic distances found in the SXRD-Pattersonmap are substantiated by results from STM. The Au coverage, recently determinedto be 3/4 of a monolayer of gold, together with SXRD leads to threenon-equivalent positions for Au within the c(8x2) unit cell. Combined withstructural information from STM topography and line profiling, two buildingblocks are identified: Au-Ge hetero-dimers within the top wire architecture andAu homo-dimers within the trenches. The incorporation of both components isdiscussed using density functional theory and model based Patterson maps bysubstituting Germanium atoms of the reconstructed Ge(001) surface.

Structural Examination of Au/Ge(001) by Surface X-Ray Diffraction and Scanning Tunneling Microscopy