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The magnetic susceptibility and magnetization of high quality single crystalbeta-TeVO4 are reported. We show that this compound, made of weakly coupledinfinite chains of VO5 pyramids sharing corners, behaves as a S = 1/2one-dimensional Heisenberg antiferromagnet. From magnetic experiments we deducethe intrachain antiferromagnetic coupling constant J/kB = 21.4 $\pm$ 0.2 K.Below 5 K a series of three phase transitions at 2.26, 3.28 and 4.65 K isobserved.

Magnetic properties of the antiferromagnetic spin-1/2 chain system $\beta$-TeVO$_{4}$