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ation SLR rates. The rates of the high-temperature flank of the SLR-NMR peaks of hexagonal LiBH4 clearly depend on resonance frequency which unequivocally reveals a low-dimensional diffusion process. Due to the very limited number of suitable model substances this makes lithium borohydride an extremely attractive material to study the effect of reduced dimensionality on Li dynamics. Most likely, the spatial confinement of Li hopping is also responsible for the very high ionic conductivity found for the hexagonal polymorph, recently.

physical review. b, condensed matter and materials physics

Fast Li diffusion in crystalline<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mtext>LiBH</mml:mtext></mml:mrow><mml:mn>4</mml:mn></mml:msub></mml:mrow></mml:math>due to reduced dimensionality: Frequency-dependent NMR spectroscopy

Fast Li diffusion in crystallineLiBH4due to reduced dimensionality: Frequency-dependent NMR spectroscopy