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Ultrahigh resolution synchrotron x-ray powder diffraction shows up two structural transitions in the layered cobaltite YBaCo2O5.50. The room-temperature orthorhombic structure transforms, on cooling below TMI≃295 K, to monoclinic coinciding with the apparition of a ferromagnetic moment and the occurrence of the metal to insulator transition. On further cooling, the ferromagnetic component disappears and orthorhombic symmetry is recovered

physical review b

Simultaneous para-ferrimagnetic, metal-insulator, and orthorhombic-monoclinic transitions in<mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msub><mml:mrow><mml:mtext>YBaCo</mml:mtext></mml:mrow><mml:mn>2</mml:mn></mml:msub><mml:msub><mml:mtext>O</mml:mtext><mml:mrow><mml:mn>5.50</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>

Simultaneous para-ferrimagnetic, metal-insulator, and orthorhombic-monoclinic transitions inYBaCo2O5.50