English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Tools annual

Global: Zendy Free Plan

Global: Zendy Tools monthly

Global: Zendy Plus monthly

The structure and vibrational spectrum of Gd3N@C80 is studied through Ramanand inelastic electron tunneling spectroscopy (IETS) as well as densityfunctional theory (DFT) and universal force field (UFF) calculations. Hinderedrotations, shown by both theory and experiment, indicate the formation of aGd3N-C80 bond which reduces the ideal icosahedral symmetry of the C80 cage. Thevibrational modes involving the movement of the encapsulated species are afingerprint of the interaction between the fullerene cage and the core complex.We present Raman data for the Gd3N@C2n (40 < n < 44) family as well as Y3N@C80,Lu3N@C80, and Y3N@C88 for comparison. Conductance measurements have beenperformed on Gd3N@C80 and reveal a Kondo effect similar to that observed inC60.

Investigation of Gd3N@C2n (40 < n < 44) family by Raman and inelastic electron tunneling spectroscopy