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BaIrO3 is a novel insulator with coexistent weak ferromagnetism, charge andspin density wave. Dilute RE doping for Ba induces a metallic state, whereasapplication of modest pressure readily restores an insulating statecharacterized by a three-order-of-magnitude increase of resistivity. Sincepressure generally increases orbital overlap and broadens energy bands, apressure-induced insulating state is not commonplace. The profoundly dissimilarresponses of the ground state to light doping and low hydrostatic pressuressignal an unusual, delicate interplay between structural and electronic degreesof freedom in BaIrO3.

Pressure-Induced Insulating State in Ba1-xRExIrO3 (RE = Gd, Eu) Single Crystals