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A wide-range doping was achieved by a high-pressure method for TbFeAsO1-xfrom "under doped" to "over doped" superconducting compositions throughout theoptimized superconductivity (Tc of 44 K). Tc vs. lattice constant shows adome-shaped feature, while Tc vs. the lattice constant likely follows a uniqueempirical curve over the doping range. The relatively large amount of oxygenvacancies up to 0.3 per the formula unit was introduced possibly because of thesmaller replacement Tb than the other Ln (rare-earth element) in the LnFeAsO1-xsystem.

Superconducting properties of the oxygen-vacant iron oxyarsenide TbFeAsO1-x from underdoped to overdoped compositions