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We report the crystal structure and unconventional magnetic ordering ofCs_2Cu_3CeF_{12}, which is composed of buckled kagome lattice of Cu^{2+} ions.The exchange network in the buckled kagome lattice is fairly anisotropic, sothat the present spin system can be divided into two subsystems: alternatingHeisenberg chains with strong antiferromagnetic exchange interactions anddangling spins. Although the direct exchange interactions between neighboringspins were found to be all antiferromagnetic, ferromagnetic magnetic orderingof the dangling spins was observed. Magnetization exhibits a plateau atone-third of the saturation magnetization. These observations can be understoodin terms of the indirect interaction between dangling spins mediated by thechain spin.

Partial ferromagnetic ordering and indirect exchange interaction in spatially anisotropic kagome antiferromagnet Cs_2Cu_3CeF_{12}